Between You and Me is used for secrets, not to be shared with other people. Example: #1) I think Mary might be dating someone new, but that's just between you and me. #2) Between you and me, I'm going to divorce my husband. #3) Between you and me, my older brother has is overly fond of sheep.
Between Jobs means you are unemployed; you left one job and expect to start another. Example: #1) I am between jobs now. I have been between jobs for almost six months.
Between (Places) Example: #1) There aren't any gas stations between this city and the next one. #2) The grocery store is between my home and office, so I can stop there on the way home. #3) The gunman shot the sheriff right between the eyes.
Between (Times) - Example: #1) I will come home between 7pm and 8pm tonight. #2) Sometime between this morning and last night, somebody stole my car. #3) It will take between 6 and 8 hours to do all the work. #4) After he cut his wrists, it took between 45 minutes and an hour for him to die.
To Choose Between Something and Something Else - Example: #1) I had to choose between a low paying job that I love or a high paying job that I hate. I chose the job that I love. #2) I had to choose between a rich husband that neglects me and a poor man that treats me well. I stayed single. #3) I only had enough money to send one of my children to university, so I had to choose between my son and daughter. #4) You can choose between two flavors, French Vanilla and Toffee.
The Difference Between is used to describe how two things are different. Example: #1) There are a lot of differences between my brother and I. He is athletic and I spend all day on adult websites. #2) The difference between this computer and that one is the speed and the size of the hard drive.